that’s fine and all but the problem with the debian based SteamOS were the horribly outdated GPU drivers.
SteamOS doesn't use plain upstream GPU drivers. Back when SteamOS 3 was announced, Valve employees said in interviews that switching to an Arch base would allow them to more frequently update the OS, yes, but now with SteamOS 3 being out since quite some time it became clear that this is simply not the case. Big Arch package syncs are a rare occurrence, kernel and Mesa are maintained in their own downstream branches.
The charging controller must support that feature. Notebooks by Asus, Lenovo and maybe others do, perhaps even the Ally and Legion handhelds, but if the battery controller doesn't support that, the toggle will do nothing.