It's a very recent one but my answer right now has to be Arcane, season 2, episode 7. It's a brilliant show from start to finish but this episode in particular is such a gut punch it still hurts to think about.
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Star Trek TNG S6E21 Where Riker gets put through psychological hell in magnificent fashion. It spells out clearly everything that's terrifying about psychedelics, and mental hospitals commandeering your life with discrediting tactics.
Also I love the wrestling episode of King of the Hill because Bobby and Connie subvert expectations of warring adults in grand fashion!
The circle of life episode of Adventure time is such a blast! Very trippy.
Honorable mention for my favorite moment in a TV show - Brienne of Tarth a Knight of the Seven Kingdoms. What a shining, glorious moment of satisfaction for a hardworking and truly good character in a season of utter bullshit.
I will always feel that we were robbed of so many satisfying conclusions because of the show rushing to wrap everything up. Not everything had to be tied in a perfect bow, but what we got certainly did not scratch that perfectly placed itch.
It's an absolute travesty that they threw away nearly every character's arc in the final season and robbed them of their big moments, purely to subvert expectations. These arcs were predictable because that's where their stories were fucking heading. But noOoOoo...
Jaime is probably the show's finest example of an eight-season arc thrown directly into the trash at the last moment. What was even the point?
I understand they wanted some characters to be disappointments, it could have been cool to have Jaime get super close to a satisfying arc and, at the last second fail. But the last few scenes with him completely backpedalling his entire motivation make no sense.
GOT had so much going for it. And yet, in a post like this asking about favorite episodes, no one is even mentioning it's earlier fantastic episodes - the final season ruined all previous good work.
Maybe not favorite of all shows but the first that came to mind;
Out of Gas, Firefly
Take my love
Take my land
Take me where I cannot stand
I don't care 'cause I'm still free
You can't take the sky from me
Agents of shield s3 e 13, why? A spies goodbye, if you know, you know. https://www.youtube.com/watch?v=dpRssodHXks
Will not spoil it, but I absolutely love/loved the series finale episode of Summer Camp Island. Such a wholesome ending with such a good payoff, in my opinion, to everything that happens in the later seasons when the show decided "we want to be a story driven series!" more than the first and maybe 2nd season.
Babylon 5: Severed Dreams
IYKYK
What We Do In the Shadows, "Baron's Night Out". Absolutely hilarious. The vampires getting high drinking the blood of high people is great comedy.
I don’t think this has been mentioned yet and might not be seen but…
The finale of Six Feet Under. It’s my favorite show, and the finale is the only episode of a show (other than maybe Futurama) that made me cry. I can’t even explain why, and there’s so many other episodes of SixFUnder that are incredible, but I’ve never in my life seen a show end that strong, and it’s my favorite show.
The gay episode of The Last of Us. I think it's the greatest episode of television period.
A lot of great shows aren't coming to mind, but one great show is:
Atlanta - The Goof Who Sat by the Door (Season 4, Episode 8)
Without a doubt top 5 funniest episodes of anything I've ever seen. This show was absolutely brilliant, with a lot of great episodes, but this one was... chefs kiss